Methyl Methacrylate → HCID 22173653, compound

HRID 1015674Notes

Reaction equation

HRID 1015674 reaction equation
[C:1]([O:6][CH3:7])(=[O:5])[C:2]([CH3:4])=[CH2:3].[C:8]([O:12][CH3:13])(=[O:11])[CH:9]=[CH2:10].C(S)CCCCCCC>C1(C)C(C)=CC=CC=1>[C:1]([O:6][CH3:7])(=[O:5])[C:2]([CH3:4])=[CH2:3].[C:8]([O:12][CH3:13])(=[O:11])[CH:9]=[CH2:10]

Participants

5

Reactant 3

HCID 6658Methyl MethacrylateHCID 7294Methyl AcrylateHCID 81441-Octanethiol

Product 1

HCID 22173653HCID 22173653, compound

Reagents, catalysts & solvents 1

HCID 7237O-XyleneSolvent

Procedure

To a monomer mixture including 89.2 parts by mass of methyl methacrylate, 5.8 parts by mass of methyl acrylate and 5 parts by mass of xylene, 0.0294 part by mass of 1,1-di-t-butylperoxy-3,3,5-trimethyl cyclohexane and 0.115 part by mass of n-octylmercaptan were added and uniformly mixed therein. The solution was continuously supplied to a sealed type pressure resistant reactor having an inner volume of 10 L. Polymerization reaction is carried out at an average temperature of 130° C. for an average retention time of two hours while stirring, and then the reaction solution was continuously transferred to a storage tank with deaeration equipment connected to the reactor to remove volatile portions therefrom. The melted solution was further continuously transferred to an extruder to obtain pellets of a (methyl methacrylate-methyl acrylate) (b-1) copolymer.

Workup

  1. additionwere added
  2. additionuniformly mixed
  3. customThe solution was continuously supplied to a sealed type pressure resistant reactor
  4. customPolymerization reaction
  5. customis carried out at an average temperature of 130° C. for an average retention time of two hours
  6. customto remove volatile portions

Sources & evidence

ORD record
ord-9e1e83939cda45ab9785556a8f614488
Source dataset
uspto-grants-2011_07
Patent number
US07985803B2

Reaction notes

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