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HRID1086777

反应详情

EQUATION

反应方程式

HRID 1086777 的结构方程式

REACTANTS

反应物

4
结构：O=Cc1ccc(O)cc1
HCID126

4-Hydroxybenzaldehyde

C7H6O2

结构：c1ccc(P(c2ccccc2)c2ccccc2)cc1
HCID11776

Triphenylphosphine

C18H15P

结构：CCOC(=O)N=NC(=O)OCC
HCID220568

ethyl N-ethoxycarbonyliminocarbamate

C6H10N2O4

结构：CCCCC[C@H]1CC[C@H](/C=C/CO)CC1
HCID178444473

未命名化合物

PRODUCTS

生成物

1
结构：CCCCC[C@H]1CC[C@H](/C=C/COc2ccc(C=O)cc2)CC1
HCID178444466

未命名化合物

收率 60.3%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：C1CCOC1
溶剂HCID8028

Tetrahydrofuran

C4H8O

PROCEDURE

实验过程

2.9 g of 4-hydroxybenzaldehyde, 5.0 g of (E)-3-(trans-4-pentylcyclohexyl)allyl alcohol, 4.1 g of diethyl azodicarboxylate, 6.2 g of triphenylphosphine and 100 ml of tetrahydrofuran were reacted in an analogous manner to Example 1 to give 4.5 g of 4-[(E)-3-(trans-4-pentylcyclohexyl)allyloxy]benzaldehyde (m.p. 54-55° C.).