HRID110421

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID259

Bromide

Br-

HCID679

Dimethyl sulfoxide

C2H6OS

HCID923

Sodium ion

Na+

HCID1140

Toluene

C7H8

HCID6101

4-Methylbenzenesulfonic acid

C7H8O3S

HCID6344

Dichloromethane

CH2Cl2

HCID8023

[(Ethenyl)oxy]ethane

C4H8O

HCID8080

3,4-Dihydro-2H-pyran

C5H8O

HCID14487

Diisobutylaluminum hydride

C8H19Al

HCID70934

Furan, 2,3-dihydro-

C4H6O

结构：O=C(O)CCCC[P+](c1ccccc1)(c1ccccc1)c1ccccc1

HCID161237

未命名化合物

HCID166653

Hydride

H-

PRODUCTS

生成物

HCID10882972

Pentanoic acid, 5-(triphenylphosphoranylidene)-

C23H23O2P

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-96190d65d3d5475ab84eb0463f2c731e
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (2/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (2/10)

反应 SMILES

[Br-:39].[C:40](=[O:41])([OH:42])[CH2:43][CH2:44][CH2:45][CH2:46][P+:47]([c:48]1[cH:49][cH:50][cH:51][cH:52][cH:53]1)([c:54]1[cH:55][cH:56][cH:57][cH:58][cH:59]1)[c:60]1[cH:61][cH:62][cH:63][cH:64][cH:65]1.[CH2:77]([Cl:78])[Cl:79].[CH3:28][CH:29]([CH2:30][AlH:31][CH2:32][CH:33]([CH3:34])[CH3:35])[CH3:36].[CH3:66][c:67]1[cH:68][cH:69][cH:70][cH:71][cH:72]1.[CH3:73][S:74](=[O:75])[CH3:76].[CH:12]([O:13][CH2:14][CH3:15])=[CH2:16].[H-:37].[Na+:38].[O:1]1[CH:2]=[CH:3][CH2:4][CH2:5][CH2:6]1.[O:7]1[CH:8]=[CH:9][CH2:10][CH2:11]1.[c:17]1([CH3:18])[cH:19][cH:20][c:21]([S:22]([OH:23])(=[O:24])=[O:25])[cH:26][cH:27]1>>[C:40](=[O:41])([OH:42])[CH2:43][CH2:44][CH2:45][CH:46]=[P:47]([c:48]1[cH:49][cH:50][cH:51][cH:52][cH:53]1)([c:54]1[cH:55][cH:56][cH:57][cH:58][cH:59]1)[c:60]1[cH:61][cH:62][cH:63][cH:64][cH:65]1