Triethylamine → (4-Isopropyl-phenylethynyl)-trimethyl-silane

HRID 1117771Notes

Reaction equation

[CH3:11][Si:12]([CH3:13])([CH3:14])[C:15]#[CH:16].[CH3:17][CH2:18][N:19]([CH2:20][CH3:21])[CH2:22][CH3:23].[Cu:65][I:66].[I:1][c:2]1[cH:3][cH:4][c:5]([CH:8]([CH3:9])[CH3:10])[cH:6][cH:7]1.[Pd:24]([Cl:25])[Cl:26].[c:27]1([P:28]([c:29]2[cH:30][cH:31][cH:32][cH:33][cH:34]2)[c:35]2[cH:36][cH:37][cH:38][cH:39][cH:40]2)[cH:41][cH:42][cH:43][cH:44][cH:45]1.[c:46]1([P:47]([c:48]2[cH:49][cH:50][cH:51][cH:52][cH:53]2)[c:54]2[cH:55][cH:56][cH:57][cH:58][cH:59]2)[cH:60][cH:61][cH:62][cH:63][cH:64]1>>[c:2]1([C:16]#[C:15][Si:12]([CH3:11])([CH3:13])[CH3:14])[cH:3][cH:4][c:5]([CH:8]([CH3:9])[CH3:10])[cH:6][cH:7]1

Participants

Reactant 6

HCID 8471Triethylamine

HCID 11776Triphenylphosphine2×

HCID 24290Palladium Chloride

HCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)

HCID 66111Trimethylsilylacetylene

HCID 87073p-Iodocumene

Product 1

HCID 23390603(4-Isopropyl-phenylethynyl)-trimethyl-silane

Sources & evidence

ORD record: ord-a3614e81f17c46c2ba9a4a2dbcff0037
Source dataset: Training data from https://doi.org/10.1039/C8SC04228D (7/10)
DOI: 10.1039/C8SC04228D

Reaction notes

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