Hydrochloric Acid → Hexahydrofuro(2,3-b)furan-3-ol

HRID 1138335Notes

Reaction equation

HRID 1138335 reaction equation
[Al+3:18].[C:1]([O:2][CH2:3][CH:4]1[O:5][C:6](=[O:7])[CH2:8][CH:9]1[CH:10]1[O:11][CH2:12][CH2:13][O:14]1)(=[O:15])[CH3:16].[CH2:36]([CH2:37][OH:38])[CH3:39].[CH2:45]1[O:46][CH2:47][CH2:48][CH2:49]1.[CH2:55]1[O:56][CH2:57][CH2:58][CH2:59]1.[CH3:40][CH2:41][O:42][CH2:43][CH3:44].[CH3:50][CH2:51][O:52][CH2:53][CH3:54].[CH3:66][OH:67].[Cl:62][CH:63]([Cl:64])[Cl:65].[ClH:61].[H-:17].[H-:20].[H-:21].[H-:22].[Li+:19].[O:23]1[CH:24]([CH:28]([CH:29]([CH2:30][OH:31])[OH:32])[CH2:33][CH2:34][OH:35])[O:27][CH2:26][CH2:25]1.[OH2:60]>>[CH:24]12[CH:28]([CH:29]([OH:32])[CH2:30][O:31]1)[CH2:33][CH2:34][O:35]2

Participants

13

Reactant 12

HCID 313Hydrochloric AcidHCID 887MethanolHCID 962WaterHCID 10311-PropanolHCID 3283Diethyl Ether2×HCID 6212ChloroformHCID 8028Tetrahydrofuran2×HCID 28486Lithium ionHCID 104727Aluminum CationHCID 166653Hydride4×HCID 20816435[3-(1,3-Dioxolan-2-yl)-5-oxooxolan-2-yl]methyl acetateHCID 178520685HCID 178520685, compound

Product 1

HCID 9898832Hexahydrofuro(2,3-b)furan-3-ol

Sources & evidence

ORD record
ord-76d16b7f35364028b69702febc59d0e3
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (7/10)

Reaction notes

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