Diethylamine → [2-(3,5-Dichlorophenyl)ethynyl]trimethylsilane

HRID 1142023Notes

Reaction equation

HRID 1142023 reaction equation
[CH2:16]([NH:17][CH2:18][CH3:19])[CH3:20].[CH3:10][Si:11]([CH3:12])([CH3:13])[C:14]#[CH:15].[Cl:1][c:2]1[cH:3][c:4]([Cl:9])[cH:5][c:6]([I:8])[cH:7]1.[Cu:62][I:63].[Pd:21]([Cl:22])[Cl:23].[c:24]1([P:25]([c:26]2[cH:27][cH:28][cH:29][cH:30][cH:31]2)[c:32]2[cH:33][cH:34][cH:35][cH:36][cH:37]2)[cH:38][cH:39][cH:40][cH:41][cH:42]1.[c:43]1([P:44]([c:45]2[cH:46][cH:47][cH:48][cH:49][cH:50]2)[c:51]2[cH:52][cH:53][cH:54][cH:55][cH:56]2)[cH:57][cH:58][cH:59][cH:60][cH:61]1>>[Cl:1][c:2]1[cH:3][c:4]([Cl:9])[cH:5][c:6]([C:15]#[C:14][Si:11]([CH3:10])([CH3:12])[CH3:13])[cH:7]1

Participants

7

Reactant 6

HCID 8021DiethylamineHCID 11776Triphenylphosphine2×HCID 24290Palladium ChlorideHCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)HCID 66111TrimethylsilylacetyleneHCID 764241,3-Dichloro-5-iodobenzene

Product 1

HCID 22570337[2-(3,5-Dichlorophenyl)ethynyl]trimethylsilane

Sources & evidence

ORD record
ord-c474a0837bdd4735be1f08c55fc94647
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (7/10)

Reaction notes

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