3-Phenylprop-2-En-1-Ol → 3-Phenylprop-2-Enal

HRID 1421361Notes

Reaction equation

HRID 1421361 reaction equation
[CH2:1]([OH:10])[CH:2]=[CH:3][C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1.C1(=O)CCCCC1.CCCCCCCCCCCC>>[CH:1](=[O:10])[CH:2]=[CH:3][C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1

Participants

4

Reactant 3

HCID 3083-Phenylprop-2-En-1-OlHCID 7967CyclohexanoneHCID 8182Dodecane

Product 1

HCID 3073-Phenylprop-2-Enal

Procedure

1.5 g (11.2 mmol) of cinnamyl alcohol (trans-3-phenyl-2-propen-1-ol), 36 g (367 mmol) of cyclohexanone, 0.5 g of catalyst and 1.5 g of dodecane (as GC standard) were heated under argon. After the end of the reaction time, the reaction mixture was analyzed by gas chromatography and the yield was determined. The results are summarized in Table 5 below:

Sources & evidence

ORD record
ord-86f9188a6a994c66af1b0d4e3b635a76
Source dataset
uspto-grants-2000_06
Patent number
US06075145

Reaction notes

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