HRID1563565

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID3283

Diethyl Ether

C4H10O

HCID8471

Triethylamine

C6H15N

HCID11776

Triphenylphosphine

C18H15P

4 次

HCID23938

Palladium

HCID24350

Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)

CuI

HCID66111

Trimethylsilylacetylene

C5H10Si

结构：CC(C)(C)C(=O)OCC1OC(Oc2n[nH]c3cccc(Br)c23)C(OC(=O)C(C)(C)C)C(OC(=O)C(C)(C)C)C1OC(=O)C(C)(C)C

HCID178447502

未命名化合物

PRODUCTS

生成物

结构：CC(C)(C)C(=O)OCC1OC(Oc2n[nH]c3cccc(C#C[Si](C)(C)C)c23)C(OC(=O)C(C)(C)C)C(OC(=O)C(C)(C)C)C1OC(=O)C(C)(C)C

HCID178447508

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-49ebbfe2fe7c40018d903e5fcf7803dc
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (1/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (1/10)

反应 SMILES

[Br:1][c:2]1[c:3]2[c:4]([O:11][CH:12]3[CH:13]([O:14][C:15]([C:16]([CH3:17])([CH3:18])[CH3:19])=[O:20])[CH:21]([O:22][C:23]([C:24]([CH3:25])([CH3:26])[CH3:27])=[O:28])[CH:29]([O:30][C:31]([C:32]([CH3:33])([CH3:34])[CH3:35])=[O:36])[CH:37]([CH2:39][O:40][C:41]([C:42]([CH3:43])([CH3:44])[CH3:45])=[O:46])[O:38]3)[n:5][nH:6][c:7]2[cH:8][cH:9][cH:10]1.[CH3:47][Si:48]([CH3:49])([CH3:50])[C:51]#[CH:52].[CH3:53][CH2:54][N:55]([CH2:56][CH3:57])[CH2:58][CH3:59].[CH3:60][CH2:61][O:62][CH2:63][CH3:64].[Cu:142][I:143].[Pd:65].[c:104]1([P:105]([c:106]2[cH:107][cH:108][cH:109][cH:110][cH:111]2)[c:112]2[cH:113][cH:114][cH:115][cH:116][cH:117]2)[cH:118][cH:119][cH:120][cH:121][cH:122]1.[c:123]1([P:124]([c:125]2[cH:126][cH:127][cH:128][cH:129][cH:130]2)[c:131]2[cH:132][cH:133][cH:134][cH:135][cH:136]2)[cH:137][cH:138][cH:139][cH:140][cH:141]1.[c:66]1([P:67]([c:68]2[cH:69][cH:70][cH:71][cH:72][cH:73]2)[c:74]2[cH:75][cH:76][cH:77][cH:78][cH:79]2)[cH:80][cH:81][cH:82][cH:83][cH:84]1.[c:85]1([P:86]([c:87]2[cH:88][cH:89][cH:90][cH:91][cH:92]2)[c:93]2[cH:94][cH:95][cH:96][cH:97][cH:98]2)[cH:99][cH:100][cH:101][cH:102][cH:103]1>>[c:2]1([C:52]#[C:51][Si:48]([CH3:47])([CH3:49])[CH3:50])[c:3]2[c:4]([O:11][CH:12]3[CH:13]([O:14][C:15]([C:16]([CH3:17])([CH3:18])[CH3:19])=[O:20])[CH:21]([O:22][C:23]([C:24]([CH3:25])([CH3:26])[CH3:27])=[O:28])[CH:29]([O:30][C:31]([C:32]([CH3:33])([CH3:34])[CH3:35])=[O:36])[CH:37]([CH2:39][O:40][C:41]([C:42]([CH3:43])([CH3:44])[CH3:45])=[O:46])[O:38]3)[n:5][nH:6][c:7]2[cH:8][cH:9][cH:10]1