Triethylamine → 5-[(Trimethylsilyl)ethynyl]pyrimidine

HRID 1570618Notes

Reaction equation

HRID 1570618 reaction equation
[Br:1][c:2]1[cH:3][n:4][cH:5][n:6][cH:7]1.[CH3:14][CH2:15][N:16]([CH2:17][CH3:18])[CH2:19][CH3:20].[CH3:8][Si:9]([CH3:10])([CH3:11])[C:12]#[CH:13].[Cu:21][I:22]>>[c:2]1([C:13]#[C:12][Si:9]([CH3:8])([CH3:10])[CH3:11])[cH:3][n:4][cH:5][n:6][cH:7]1

Participants

5

Reactant 4

HCID 8471TriethylamineHCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)HCID 66111TrimethylsilylacetyleneHCID 783445-Bromopyrimidine

Product 1

HCID 153496695-[(Trimethylsilyl)ethynyl]pyrimidine

Sources & evidence

ORD record
ord-3247519b354248d3bebb35d7c9c393de
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (1/10)

Reaction notes

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