Potassium Iodide → HCID 136393229, compound

HRID 1594992Notes

Reaction equation

HRID 1594992 reaction equation
[OH:1][C:2]1[CH:7]=[C:6]([OH:8])[CH:5]=[CH:4][C:3]=1[C:9]1[N:14]=[C:13]([C:15]2[CH:20]=[CH:19][C:18]([OH:21])=[CH:17][C:16]=2[OH:22])[N:12]=[C:11]([C:23]2[CH:28]=[CH:27][C:26]([OH:29])=[CH:25][C:24]=2[OH:30])[N:10]=1.C(=O)([O-])[O-].[K+].[K+].[I-].[K+].[CH:39](Br)([CH3:41])[CH3:40]>COCCOCCOC>[OH:1][C:2]1[CH:7]=[C:6]([O:8][CH:39]([CH3:41])[CH3:40])[CH:5]=[CH:4][C:3]=1[C:9]1[N:10]=[C:11]([C:23]2[CH:28]=[CH:27][C:26]([O:29][CH:2]([CH3:7])[CH3:3])=[CH:25][C:24]=2[OH:30])[N:12]=[C:13]([C:15]2[CH:20]=[CH:19][C:18]([O:21][CH:5]([CH3:6])[CH3:4])=[CH:17][C:16]=2[OH:22])[N:14]=1

Participants

6

Reactant 4

HCID 4875Potassium IodideHCID 63582-BromopropaneHCID 11430Potassium CarbonateHCID 1357148802,4,6-tris(2,4-dihydroxyphenyl)-1,3,5-triazine

Product 1

HCID 136393229HCID 136393229, compound

Reagents, catalysts & solvents 1

HCID 8150DiglymeSolvent

Conditions

Temperature
140 °C

Procedure

A mixture of 50.0 g (0.123 mol ) of 2,4,6-tris(2′,4′-dihydroxyphenyl)-1,3,5-triazine, 54.6 g (0.395 mol) of potassium carbonate, 1.0 g (0.006 mol) of potassium iodide (Merck, 99.0%) and 50.1 g (0.407 mol) of isopropyl bromide (Fluka, 99.0%) in 200 ml of diethylene glycol dimethyl ether (Diglyme, Merck, >99%) is held with stirring at 140° C. under a pressure of 3.8 bar for 24 h.

Sources & evidence

ORD record
ord-0ca58f4b9d164807aff4b8a318f86ec3
Source dataset
uspto-grants-2001_09
Patent number
US06284821B1

Reaction notes

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