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HRID1608461

反应详情

EQUATION

反应方程式

HRID 1608461 的结构方程式

REACTANTS

反应物

4
结构：C=O
HCID712

Formaldehyde

CH2O

结构：OC[C@H]1O[C@@](CO)(O[C@H]2O[C@H](CO)[C@@H](O)[C@H](O)[C@H]2O)[C@@H](O)[C@@H]1O
HCID5988

Sucrose

C12H22O11

结构：[Na+].[Na+].[O]=[Cr](=[O])([O-])[O-]
HCID24488

Sodium chromate

CrNa2O4

结构：O=S(=O)([O-])O.[Na+]
HCID516919

Sodium hydrogen sulfate

HNaO4S

PRODUCTS

生成物

2
结构：O=S(=O)([O-])[O-].[Na+].[Na+]
HCID24436

Sodium sulfate anhydrous

Na2O4S

结构：O=S(=O)([O-])[O-].O=S(=O)([O-])[O-].O=S(=O)([O-])[O-].[Cr+3].[Cr+3]
HCID24930

Chromium sulfate (Cr2(SO4)3)

Cr2O12S3

PROCEDURE

实验过程

A process, as claimed in claim 1, wherein sodium hydrogen sulfate is added to the extractive liquor, to obtain a Ph value of 6-7, and the neutral sodium chromate solution is acidified with sodium hydrogen sulfate again; and further, sucrose or formaldehyde is added, followed by heating to above 100° C., to form chromium sulfate and sodium sulfate, which, after completion of reaction, are cooled to 21°-24 C., and separated, to obtain sodium sulfate decahydrate crystals and chromium sulfate.

WORKUP

后处理

  1. temperatureby heating to above 100° C.