Chloride → Ethyl 3-[tert-butyl(dimethyl)silyl]oxyhex-5-enoate

HRID 167758Notes

Reaction equation

HRID 167758 reaction equation
[C:14]([CH3:15])([CH3:16])([CH3:17])[Si:18]([O:19][CH:20]([CH2:21][C:22](=[O:23])[O:24][CH2:25][CH3:26])[CH2:27][I:28])([CH3:29])[CH3:30].[CH2:31]1[O:32][CH2:33][CH2:34][CH2:35]1.[CH3:5][N:6]1[CH2:7][CH2:8][CH2:9][N:10]([CH3:11])[C:12]1=[O:13].[CH:2](=[CH2:3])[Mg+:4].[Cl-:1].[Cu:36][I:37]>>[CH:2](=[CH2:3])[CH2:27][CH:20]([O:19][Si:18]([C:14]([CH3:15])([CH3:16])[CH3:17])([CH3:29])[CH3:30])[CH2:21][C:22](=[O:23])[O:24][CH2:25][CH3:26]

Participants

7

Reactant 6

HCID 312ChlorideHCID 8028TetrahydrofuranHCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)HCID 816462(1H)-Pyrimidinone, tetrahydro-1,3-dimethyl-HCID 76689505Ethyl 3-[tert-butyl(dimethyl)silyl]oxy-4-iodobutanoateHCID 178461832HCID 178461832, compound

Product 1

HCID 85308645Ethyl 3-[tert-butyl(dimethyl)silyl]oxyhex-5-enoate

Sources & evidence

ORD record
ord-cf22c55a813a483093ed5188b77d3182
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (9/10)

Reaction notes

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