Azobisisobutyronitrile → HCID 10154242, compound

HRID 1708848Notes

Reaction equation

HRID 1708848 reaction equation
[C:1]([O:5]CC)(=[O:4])[CH:2]=[CH2:3].[C:8]([O:13][CH3:14])(=[O:12])[C:9]([CH3:11])=[CH2:10].N(C(C)(C)C#N)=NC(C)(C)C#N>C(OCC)(=O)C>[C:8]([O:13][CH3:14])(=[O:12])[C:9]([CH3:11])=[CH2:10].[C:1]([OH:5])(=[O:4])[CH:2]=[CH2:3]

Participants

5

Reactant 3

HCID 6547AzobisisobutyronitrileHCID 6658Methyl MethacrylateHCID 8821Ethyl Acrylate

Product 1

HCID 10154242HCID 10154242, compound

Reagents, catalysts & solvents 1

HCID 8857Ethyl AcetateSolvent

Procedure

The coupler dispersion used in Sample (V) (Dispersion 1) was prepared as follows. In 50 ml of ethyl acetate was dissolved 10 g of Cyan Coupler (C-4), 2 g of ethyl acrylate, and 5 g of methyl methacrylate, and 0.2 g of azobisisobutyronitrile was added to the solution as a polymerization initiator. The mixture was allowed to react at 60° C. for 10 hours. After completion of the reaction, the reaction mixture was concentrated to a volume of 20 ml. The resulting concentrate was added to 100 ml of an aqueous solution containing 10 g of gelatin and 0.5 g of sodium dodecylbenzenesulfonate at 60° C., and the mixture was vigorously stirred in a homogenizer to prepare a dispersion.

Workup

  1. customwas prepared
  2. additionwas added to the solution as a polymerization initiator
  3. customto react at 60° C. for 10 hours
  4. customAfter completion of the reaction
  5. concentrationthe reaction mixture was concentrated to a volume of 20 ml
  6. concentrationThe resulting concentrate
  7. additionwas added to 100 ml of an aqueous solution
  8. additioncontaining 10 g of gelatin and 0.5 g of sodium dodecylbenzenesulfonate at 60° C.
  9. customto prepare a dispersion

Sources & evidence

ORD record
ord-11832f1eb7fa4b73a48badec51bab5b0
Source dataset
uspto-grants-1990_08
Patent number
US04946770

Reaction notes

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