Triethylamine → HCID 86741098, compound

HRID 1731482Notes

Reaction equation

HRID 1731482 reaction equation
O.O.O.O.O.O.[Ni:7](Cl)Cl.[NH2:10][C:11]1[C:24]2[C:23](=[O:25])[C:22]3[C:17](=[CH:18][CH:19]=[CH:20][CH:21]=3)[C:16](=[O:26])[C:15]=2[C:14]([NH2:27])=[CH:13][CH:12]=1.C(N(CC)CC)C>CN(C)C=O>[Ni+2:7].[NH2:10][C:11]1[C:24]2[C:23](=[O:25])[C:22]3[C:17](=[CH:18][CH:19]=[CH:20][CH:21]=3)[C:16](=[O:26])[C:15]=2[C:14]([NH2:27])=[CH:13][CH:12]=1

Participants

5

Reactant 3

HCID 8471TriethylamineHCID 31420Disperse Violet 1HCID 11791229Dichloronickel;hexahydrate

Product 1

HCID 86741098HCID 86741098, compound

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

Nickel (II) chloride hexahydrate (0.5 g) is dissolved in dimethylformamide (25 ml) containing 1,4-diamino anthraquinone (0.5 g) and triethylamine (0.84 g). A precipitate forms and is collected and washed repeatedly with methylene chloride until the washings are colorless. The yield is 0.66 g of a dark blue-black powder having a conductivity of 4.72×10-3S/cm. Analysis shows a composition of C--59.34 percent, H--3.76 percent, N--9.38 percent, Ni--17.2 percent and Cl--2.6 percent.

Workup

  1. customA precipitate forms and is collected
  2. washwashed repeatedly with methylene chloride until the washings

Sources & evidence

ORD record
ord-c76137e1c6e0436da3bbf7742d7de13e
Source dataset
uspto-grants-1986_11
Patent number
US04622169

Reaction notes

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