1-Hexene → HCID 20096049, compound

HRID 1770334Notes

Reaction equation

HRID 1770334 reaction equation
[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([CH3:8])=[CH:4][C:3]=1[CH:9]([CH3:16])[CH2:10][SiH:11]([O:14][CH3:15])[O:12][CH3:13].[CH2:17]=[CH:18][CH2:19][CH2:20][CH2:21][CH3:22]>C(O)(C)C.[H+].[H+].Cl[Pt-2](Cl)(Cl)(Cl)(Cl)Cl>[CH3:13][O:12][Si:11]([O:14][CH3:15])([CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22])[CH2:10][CH:9]([C:3]1[CH:4]=[C:5]([CH3:8])[CH:6]=[CH:7][C:2]=1[CH3:1])[CH3:16]

Participants

5

Reactant 2

HCID 115971-HexeneHCID 131718842HCID 131718842, compound

Product 1

HCID 20096049HCID 20096049, compoundYield 59.5%

Reagents, catalysts & solvents 2

HCID 61859Chloroplatinic acidCatalystHCID 3776IsopropanolSolvent

Procedure

In the same apparatus and procedures as EXAMPLE 1, 12.7 g (0.049 mole) of 3-(2,5-dimethylphenyl)-1,1-dimethoxy-1-silabutane, 13.1 g (0.15 mole) of 1-hexene, and 90 μl of 1% chloroplatinic acid in isopropanol were placed under the dry nitrogen atmosphere. The reactor was refluxed for 3 hours. Vacuum distillation of the reaction products gave 9.4 g (bp, 131°-3° C./0.6 mmHg) of 4,4-dimethoxy-2-(2,5-dimethylphenyl)-4-siladecane.

Workup

  1. temperatureThe reactor was refluxed for 3 hours
  2. distillationVacuum distillation of the reaction products

Sources & evidence

ORD record
ord-b52b145f48004533afeceece5d77e9f3
Source dataset
uspto-grants-1995_01
Patent number
US05386050

Reaction notes

Loading…