Methane → C.I. Fluorescent Brightening Agent 28, (E)-

HRID 1836072Notes

Reaction equation

HRID 1836072 reaction equation
[OH-:1].[NH4+].[Na].S(=O)(=O)(O)O.[CH2:9]1[N:14]([C:15]2[N:20]=[C:19]([NH:21][C:22]3[CH:27]=[CH:26][C:25](/[CH:28]=[CH:29]/[C:30]4[CH:35]=[CH:34][C:33]([NH:36][C:37]5[N:42]=[C:41]([NH:43][C:44]6[CH:49]=[CH:48][CH:47]=[CH:46][CH:45]=6)[N:40]=[C:39]([N:50]6[CH2:55][CH2:54][O:53][CH2:52][CH2:51]6)[N:38]=5)=[CH:32][C:31]=4[S:56]([O-:59])(=[O:58])=[O:57])=[C:24]([S:60]([O-:63])(=[O:62])=[O:61])[CH:23]=3)[N:18]=[C:17]([NH:64][C:65]3[CH:70]=[CH:69][CH:68]=[CH:67][CH:66]=3)[N:16]=2)[CH2:13][CH2:12][O:11][CH2:10]1.[Na+].[Na+].C.[OH2:74]>>[CH:47]1[CH:46]=[CH:45][C:44]([NH:43][C:41]2[N:40]=[C:39]([N:50]([CH2:51][CH2:52][OH:1])[CH2:55][CH2:54][OH:53])[N:38]=[C:37]([NH:36][C:33]3[CH:34]=[CH:35][C:30](/[CH:29]=[CH:28]/[C:25]4[CH:26]=[CH:27][C:22]([NH:21][C:19]5[N:18]=[C:17]([NH:64][C:65]6[CH:70]=[CH:69][CH:68]=[CH:67][CH:66]=6)[N:16]=[C:15]([N:14]([CH2:9][CH2:10][OH:11])[CH2:13][CH2:12][OH:74])[N:20]=5)=[CH:23][C:24]=4[S:60]([OH:63])(=[O:61])=[O:62])=[C:31]([S:56]([OH:59])(=[O:57])=[O:58])[CH:32]=3)[N:42]=2)=[CH:49][CH:48]=1

Participants

7

Reactant 6

HCID 297MethaneHCID 962Water2×HCID 1118Sulfuric AcidHCID 14923Ammonium HydroxideHCID 5360545SodiumHCID 643365716090-02-1

Product 1

HCID 6108780C.I. Fluorescent Brightening Agent 28, (E)-

Procedure

A mixture of V8vEGTDEL polyhedral inclusion bodies (13.0 g of technical material, 6.0 g of PIBs, about 1.27×1011 PIBs/gram, mean PIB size about 2.5 μm) and ammonium hydroxide solution (15.0 g, pH 9.5) is stirred for 15 minutes, treated with REAX® 85A (0.18 g, a sodium lignosulfonate available from Westvaco, Charleston Heights, S.C.), stirred for 15 minutes, treated with Indulin® C (12.0 g of a 2% solution, pH 11, a sodium lignate available from Westvaco), stirred for one hour, and adjusted slowly to pH 4.5 with dilute sulfuric acid over 2.5 hours. After stirring for 45 minutes, the polyhedral inclusion body mixture is mixed with the copolymer slurry described in Example 2 (56.6 g), Blancophor BBH (14.70 g), talc (3.21 g), charcoal (9.0 g), a solution of Calcofluor M2R (3.30 g) in water, and water to obtain a slurry. The slurry is filtered through an 80 mesh screen and spray dried using a Büchi spray drier (model 190) to obtain the coated pesticidal matrix identified as composition 33 in Table VII.

Workup

  1. stirring), stirred for 15 minutes
  2. stirringAfter stirring for 45 minutes
  3. additionthe polyhedral inclusion body mixture is mixed with the copolymer slurry

Sources & evidence

ORD record
ord-76b7ac93599b4f888de7db5efad7befd
Source dataset
uspto-grants-2004_08
Patent number
US06776996B2

Reaction notes

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