Cyanuric chloride → HCID 87664814, compound

HRID 1868441Notes

Reaction equation

HRID 1868441 reaction equation
[Mg].Br[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[N:19]1[C:26](Cl)=[N:25][C:23]([Cl:24])=[N:22][C:20]=1[Cl:21]>O1CCCC1>[Cl:21][C:20]1[N:22]=[C:23]([Cl:24])[N:25]=[C:26]([CH2:18][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH3:3])[N:19]=1

Participants

5

Reactant 3

HCID 7954Cyanuric chlorideHCID 82131-BromohexadecaneHCID 5462224Magnesium2×

Product 1

HCID 87664814HCID 87664814, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent3×

Conditions

Temperature
65 °C

Procedure

2.7 g of magnesium was added to 200 ml of tetrahydrofuran and stirred until the magnesium was completely dissolved. To the solution was added dropwise a solution of bromohexadecane (31.1 g) in tetrahydrofuran (200 ml). Thereafter, the resulting solution was heated to 65° C. and reacted for 6 hours with stirring. The reaction solution was slowly added dropwise to a solution of cyanuric chloride (15 g) in tetrahydrofuran (250 ml), and reacted for 12 hours. After completion of the reaction, the resulting solution was evaporated under reduced pressure to obtain a concentrate and then the concentrate was purified by distillation in vacuo to yield pure 2,4-dichloro-6-hexadecyl-1,3,5-triazine.

Workup

  1. dissolutionwas completely dissolved
  2. customreacted for 6 hours
  3. customreacted for 12 hours
  4. customAfter completion of the reaction
  5. customthe resulting solution was evaporated under reduced pressure
  6. customto obtain
  7. concentrationa concentrate
  8. distillationthe concentrate was purified by distillation in vacuo

Sources & evidence

ORD record
ord-74639be74e6847c7b8714f24b4c7b919
Source dataset
uspto-grants-2009_12
Patent number
US07635746B2

Reaction notes

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