N-vinyl-2-pyrrolidone → 1,3,5-Trimethoxybenzene

HRID 1882698Notes

Reaction equation

HRID 1882698 reaction equation
C=CN1CCCC1=O.O=S(=O)(Oc1ccccc1)C(F)(F)F>Cc1cc(C)c(-n2cc[n+](-c3c(C)cc(C)cc3C)c2)c(C)c1.[Cl-].CC(C)(C)[O-].[K+].CCN(CC)CC.CN(C)C=O.C1=C\CC/C=C\CC/1.C1=C\CC/C=C\CC/1.[Ni]>COc1cc(OC)cc(OC)c1.O=C1CCCN1/C=C/c1ccccc1.C=C(c1ccccc1)N1CCCC1=O

Participants

10

Reactant 2

HCID 6917N-vinyl-2-pyrrolidoneHCID 548641Phenyl Trifluoromethanesulfonate

Product 3

HCID 693011,3,5-TrimethoxybenzeneHCID 5371898HCID 5371898, compoundHCID 110196022-Pyrrolidinone, 1-(1-phenylethenyl)-

Reagents, catalysts & solvents 5

HCID 8471TriethylamineReagentHCID 27342111,3-Bis(2,4,6-trimethylphenyl)imidazolium chlorideCatalystHCID 23665647Potassium tert-butoxideCatalystHCID 6228DimethylformamideSolventHCID 6433264Bis(1,5-cyclooctadiene)nickelOther

Conditions

Temperature
85 °C

Workup

  1. additionKeep Filtrate

Sources & evidence

ORD record
ord-69db896f8907426390940c76356e96d6
Source dataset
N-vinyl pyrrolidone Mizoroki-Heck

Reaction notes

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