N-vinyl-2-pyrrolidone → 1,3,5-Trimethoxybenzene

HRID 1882707Notes

Reaction equation

HRID 1882707 reaction equation
C=CN1CCCC1=O.Ic1ccccc1>CC(C)(C)P(c1ccccc1-c1ccccc1)C(C)(C)C.CCN(CC)CC.CN(C)C=O.C1=C\CC/C=C\CC/1.C1=C\CC/C=C\CC/1.[Ni]>COc1cc(OC)cc(OC)c1.O=C1CCCN1/C=C/c1ccccc1.C=C(c1ccccc1)N1CCCC1=O

Participants

9

Reactant 2

HCID 6917N-vinyl-2-pyrrolidoneHCID 11575Iodobenzene

Product 3

HCID 693011,3,5-TrimethoxybenzeneHCID 5371898HCID 5371898, compoundHCID 110196022-Pyrrolidinone, 1-(1-phenylethenyl)-

Reagents, catalysts & solvents 4

HCID 8471TriethylamineReagentHCID 27342152-(Di-tert-butylphosphino)biphenylCatalystHCID 6228DimethylformamideSolventHCID 6433264Bis(1,5-cyclooctadiene)nickelOther

Conditions

Temperature
85 °C

Workup

  1. additionKeep Filtrate

Sources & evidence

ORD record
ord-d7067e03c5214d1abc54039cb3abe85f
Source dataset
N-vinyl pyrrolidone Mizoroki-Heck

Reaction notes

Loading…