N-vinyl-2-pyrrolidone → 1,3,5-Trimethoxybenzene

HRID 1882711Notes

Reaction equation

HRID 1882711 reaction equation
C=CN1CCCC1=O.Ic1ccccc1>CN(C)c1ccccc1-c1ccccc1P(C1CCCCC1)C1CCCCC1.CCN(CC)CC.CN(C)C=O.C1=C\CC/C=C\CC/1.C1=C\CC/C=C\CC/1.[Ni]>COc1cc(OC)cc(OC)c1.O=C1CCCN1/C=C/c1ccccc1.C=C(c1ccccc1)N1CCCC1=O

Participants

9

Reactant 2

HCID 6917N-vinyl-2-pyrrolidoneHCID 11575Iodobenzene

Product 3

HCID 693011,3,5-TrimethoxybenzeneHCID 5371898HCID 5371898, compoundHCID 110196022-Pyrrolidinone, 1-(1-phenylethenyl)-

Reagents, catalysts & solvents 4

HCID 8471TriethylamineReagentHCID 27342172-(Dicyclohexylphosphino)-2'-(dimethylamino)biphenylCatalystHCID 6228DimethylformamideSolventHCID 6433264Bis(1,5-cyclooctadiene)nickelOther

Conditions

Temperature
85 °C

Workup

  1. additionKeep Filtrate

Sources & evidence

ORD record
ord-d1b4e2ef2f904a9181a7cc4e8ea51f8b
Source dataset
N-vinyl pyrrolidone Mizoroki-Heck

Reaction notes

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