N-vinyl-2-pyrrolidone → 1,3,5-Trimethoxybenzene

HRID 1882737Notes

Reaction equation

HRID 1882737 reaction equation
C=CN1CCCC1=O.Ic1ccccc1>CC1(C)c2cccc(P(c3ccccc3)c3ccccc3)c2Oc2c(P(c3ccccc3)c3ccccc3)cccc21.CCN(CC)CC.CN(C)C=O.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.[Pd].[Pd]>COc1cc(OC)cc(OC)c1.O=C1CCCN1/C=C/c1ccccc1.C=C(c1ccccc1)N1CCCC1=O

Participants

9

Reactant 2

HCID 6917N-vinyl-2-pyrrolidoneHCID 11575Iodobenzene

Product 3

HCID 693011,3,5-TrimethoxybenzeneHCID 5371898HCID 5371898, compoundHCID 110196022-Pyrrolidinone, 1-(1-phenylethenyl)-

Reagents, catalysts & solvents 4

HCID 8471TriethylamineReagentHCID 6360441,1'-(9,9-Dimethyl-9H-xanthene-4,5-diyl)bis(1,1-diphenylphosphine)CatalystHCID 6228DimethylformamideSolventHCID 9811564Bis(dibenzylideneacetone)palladiumOther

Conditions

Temperature
85 °C

Workup

  1. additionKeep Filtrate

Sources & evidence

ORD record
ord-264a6cd8a3834fcabfe93393fbcd24a9
Source dataset
N-vinyl pyrrolidone Mizoroki-Heck

Reaction notes

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