Tributylstannane → 4-Tributylstannyl-3,6-dihydro-2H-pyran

HRID 192969Notes

Reaction equation

HRID 192969 reaction equation
[CH2:13]([CH2:14][CH2:15][CH3:16])[SnH:17]([CH2:18][CH2:19][CH2:20][CH3:21])[CH2:22][CH2:23][CH2:24][CH3:25].[CH2:1]([Li:2])[CH2:3][CH2:4][CH3:5].[CH3:33][CH2:34][N:35]([CH2:36][CH3:37])[CH2:38][CH3:39].[CH3:40][S:41](=[O:42])(=[O:43])[Cl:44].[CH3:50][CH2:51][CH2:52][CH2:53][CH2:54][CH3:55].[CH:6]([NH:7][CH:8]([CH3:9])[CH3:10])([CH3:11])[CH3:12].[O:26]1[CH2:27][CH2:28][C:29](=[O:32])[CH2:30][CH2:31]1.[O:45]1[CH2:46][CH2:47][CH2:48][CH2:49]1>>[CH2:13]([CH2:14][CH2:15][CH3:16])[Sn:17]([CH2:18][CH2:19][CH2:20][CH3:21])([CH2:22][CH2:23][CH2:24][CH3:25])[C:29]1=[CH:28][CH2:27][O:26][CH2:31][CH2:30]1

Participants

9

Reactant 8

HCID 5948TributylstannaneHCID 7912DiisopropylamineHCID 8028TetrahydrofuranHCID 8058HexaneHCID 8471TriethylamineHCID 31297Methanesulfonyl chlorideHCID 121599Tetrahydro-4H-pyran-4-oneHCID 178418339Butyllithium

Product 1

HCID 222522584-Tributylstannyl-3,6-dihydro-2H-pyran

Sources & evidence

ORD record
ord-54e3d2e31b8c4154a84143122de8512b
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (6/10)

Reaction notes

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