Dimethyl Sulfoxide → 4-Benzoyloxy-1-ethoxy-2,2,6,6-tetramethylpiperidine

HRID 195744Notes

Reaction equation

HRID 195744 reaction equation
[C:1]([c:2]1[cH:3][cH:4][cH:5][cH:6][cH:7]1)(=[O:8])[O:9][CH:10]1[CH2:11][C:12]([CH3:19])([CH3:20])[N:13]([OH:18])[C:14]([CH3:16])([CH3:17])[CH2:15]1.[CH2:27]([CH3:28])[I:29].[CH3:34][S:35](=[O:36])[CH3:37].[H-:32].[Mg+2:21].[NH2:30][OH:31].[Na+:33].[O-:22][S:23](=[O:24])(=[O:25])[O-:26].[O:38]1[CH2:39][CH2:40][CH2:41][CH2:42]1.[OH2:43]>>[C:1]([c:2]1[cH:3][cH:4][cH:5][cH:6][cH:7]1)(=[O:8])[O:9][CH:10]1[CH2:11][C:12]([CH3:19])([CH3:20])[N:13]([O:18][CH2:27][CH3:28])[C:14]([CH3:16])([CH3:17])[CH2:15]1

Participants

11

Reactant 10

HCID 679Dimethyl SulfoxideHCID 787HydroxylamineHCID 888Magnesium CationHCID 923Sodium ionHCID 962WaterHCID 1117Sulfate IonHCID 6340IodoethaneHCID 8028TetrahydrofuranHCID 166653HydrideHCID 6881781-Hydroxy-4-benzoyloxy-2,2,6,6-tetramethylpiperidine

Product 1

HCID 193917364-Benzoyloxy-1-ethoxy-2,2,6,6-tetramethylpiperidine

Sources & evidence

ORD record
ord-3db25a6ca24a4ff9b07e7e5fd8feb983
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (6/10)

Reaction notes

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