O-Cresol → o-CRESYL GLYCIDYL ETHER

HRID 2059083Notes

Reaction equation

HRID 2059083 reaction equation
[C:1]1([CH3:8])[C:6]([OH:7])=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH2:9]([CH:11]1[O:13][CH2:12]1)Cl>N1CCCCC1>[O:13]1[CH2:12][CH:11]1[CH2:9][O:7][C:6]1[CH:5]=[CH:4][CH:3]=[CH:2][C:1]=1[CH3:8]

Participants

4

Reactant 2

HCID 335O-CresolHCID 7835Epichlorohydrin

Product 1

HCID 16640o-CRESYL GLYCIDYL ETHER

Reagents, catalysts & solvents 1

HCID 8082PiperidineCatalyst

Procedure

A solution of ortho-cresol (64.8 g., 0.6 mole), epichlorohydrin (330 g., 3.6 mole), and piperidine (5 drops) was allowed to react and the product was isolated using the same methods outlined hereinabove in Example 1. Concentration of the methylene chloride extract gave 95 g. of crude epoxide (IIb) which was used without further purification.

Workup

  1. customto react
  2. customthe product was isolated
  3. extractionConcentration of the methylene chloride extract
  4. customgave 95 g
  5. customof crude epoxide (IIb) which was used without further purification

Sources & evidence

ORD record
ord-90a8cd89dff7435b90f89e7d01cc8385
Source dataset
uspto-grants-1982_03
Patent number
US04321398

Reaction notes

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