Acetate → 4-Methyl-2-phenylquinoline

HRID 2138068Notes

Reaction equation

HRID 2138068 reaction equation
[C:41](=[O:42])([O-:43])[O-:44].[CH3:56][CH2:57][O:58][C:59](=[O:60])[CH3:61].[CH3:62][O:63][CH2:64][CH2:65][O:66][CH3:67].[Cl:1][c:2]1[n:3][c:4]2[cH:5][cH:6][cH:7][cH:8][c:9]2[c:10]([CH3:12])[cH:11]1.[K+:45].[K+:46].[O-:48][C:49]([CH3:50])=[O:51].[O-:52][C:53]([CH3:54])=[O:55].[Pd+2:47].[c:13]1([B:19]([OH:20])[OH:21])[cH:14][cH:15][cH:16][cH:17][cH:18]1.[c:22]1([P:23]([c:24]2[cH:25][cH:26][cH:27][cH:28][cH:29]2)[c:30]2[cH:31][cH:32][cH:33][cH:34][cH:35]2)[cH:36][cH:37][cH:38][cH:39][cH:40]1>>[c:2]1(-[c:13]2[cH:14][cH:15][cH:16][cH:17][cH:18]2)[n:3][c:4]2[cH:5][cH:6][cH:7][cH:8][c:9]2[c:10]([CH3:12])[cH:11]1

Participants

10

Reactant 9

HCID 175Acetate2×HCID 813Potassium Cation2×HCID 80711,2-DimethoxyethaneHCID 8857Ethyl AcetateHCID 11776TriphenylphosphineHCID 19660Carbonate IonHCID 66827Phenylboronic AcidHCID 694492-Chloro-4-methylquinolineHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)

Product 1

HCID 209194-Methyl-2-phenylquinoline

Sources & evidence

ORD record
ord-abc69020559a48c2802d582439f85c26
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (4/10)

Reaction notes

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