Nitrogen → Ammonium Persulfate

HRID 2206655Notes

Reaction equation

HRID 2206655 reaction equation
[N:1]#N.C(OC)(=O)[C:4]([CH3:6])=[CH2:5].[NH2:10][C@H:11]([C:14](O)=O)[CH2:12][CH3:13].[C:17]([O-:20])([OH:19])=[O:18].[Na+:21].[S:22]([O:26][O:27][S:28]([O-:31])(=[O:30])=[O:29])([O-:25])(=[O:24])=[O:23].[NH4+].[NH4+]>O>[Na+:21].[S:22]([O-:26])([O:20][CH2:17][CH2:13][CH2:12][CH2:11][CH2:14][CH2:14][CH2:11][CH2:12][CH2:13][CH2:5][CH2:4][CH3:6])(=[O:24])=[O:23].[C:17]([O-:20])([OH:19])=[O:18].[Na+:21].[S:22]([O:26][O:27][S:28]([O-:31])(=[O:30])=[O:29])([O-:25])(=[O:24])=[O:23].[NH4+:10].[NH4+:1]

Participants

9

Reactant 5

HCID 947NitrogenHCID 6658Methyl MethacrylateHCID 62648Ammonium PersulfateHCID 80283(-)-2-Aminobutyric acidHCID 516892Sodium Bicarbonate

Product 3

HCID 62648Ammonium PersulfateHCID 516892Sodium BicarbonateHCID 3423265Sodium Lauryl Sulfate

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

A 1 L reactor consisting of a stirrer, cooling equipment feedline inert gas (N2), the feed tank pre-emulsion, bath temperature control and metering pump. Were added from 160 to 220 g of MMA (methyl methacrylate), of 20 to 80 g Abu (butyl acrylate), 2.0 to 3.0 g of surfactant, of between 3.5 and 5.5 g of NaHCO3 and between 8.0 and 9.0 g of APS (ammonium persulfate). The reactor was heated in a temperature range between 70 and 85° C. and into it was added reagents for the pre-emulsion, of between 0.5 and 2.0 g of the monomer mixture, between 1.0 and 3.0 g of lauryl sulfate sodium, 80 to 110 g of NaHCO3, between 15 and 20 g of APS and the remaining water to obtain a solid theoretical rate of about 40%.

Workup

  1. customA 1 L reactor consisting of a stirrer
  2. temperatureThe reactor was heated in a temperature range between 70 and 85° C. and into it
  3. additionwas added reagents for the pre-emulsion

Sources & evidence

ORD record
ord-546bdcf330b14bcb9fdcdb0e9c542f37
Source dataset
uspto-grants-2016_06
Patent number
US09371588B2

Reaction notes

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