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HRID22343

反应详情

EQUATION

反应方程式

HRID 22343 的结构方程式

REACTANTS

反应物

4
结构：COC(C)(C)C
HCID15413

Methyl tert-butyl ether

C5H12O

结构：c1ccc(C2CCNCC2)cc1
HCID69873

4-Phenylpiperidine

C11H15N

结构：O=C([O-])/C=C/C(=O)[O-]
HCID5460307

Fumerate

C4H2O4-2

结构：COc1cc2oc(=O)c3c(c2cc1OCCCCOS(C)(=O)=O)CCC3
HCID19927634

未命名化合物

PRODUCTS

生成物

1
结构：COc1cc2oc(=O)c3c(c2cc1OCCCCN1CCC(c2ccccc2)CC1)CCC3
HCID19927653

未命名化合物

收率 73%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CC(C)O
溶剂HCID3776

Isopropanol

C3H8O

PROCEDURE

实验过程

Method B (16 h at 60° C.); starting materials: 2,3-dihydro-8-[4-(methanesulfonyloxy)butyloxy]-7-methoxy-cyclopenta[c][1]-benzopyran-4(1H)-one (example 84) and 4-phenylpiperidine; yield 73%; fusion point 104°-105° C. (from TBME). Fumarate: method E; yield 77%; fusion point 192°-193° C. (from isopropanol).

WORKUP

后处理

  1. customMethod B (16 h at 60° C.)