Azobisisobutyronitrile → HCID 20434190, compound

HRID 2296883Notes

Reaction equation

HRID 2296883 reaction equation
[OH:1][CH2:2][CH2:3][O:4][C:5](=[O:8])[CH:6]=[CH2:7].[CH3:9][O:10][C:11](=[O:15])[C:12]([CH3:14])=[CH2:13].CC(N=NC(C#N)(C)C)(C#N)C>C1COCC1>[OH:1][CH2:2][CH2:3][O:4][C:5](=[O:8])[CH:6]=[CH2:7].[CH3:9][O:10][C:11](=[O:15])[C:12]([CH3:14])=[CH2:13]

Participants

5

Reactant 3

HCID 6547AzobisisobutyronitrileHCID 6658Methyl MethacrylateHCID 131652-Hydroxyethyl acrylate

Product 1

HCID 20434190HCID 20434190, compoundYield 80%

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Conditions

Temperature
67.5 °C

Procedure

To a 500 ml round-bottom flask was added 0.3 mole of 9-anthracenemethylacrylate, 0.5 mole of 2-hydroxyethylacrylate, 0.2 mole of methylmethacrylate, 300 g of THF, and 0.1-3 g of AIBN. The resulting solution was stirred at 60-75° C. for 5-20 hours under nitrogen atmosphere. The reaction mixture was precipitated in ethyl ether or n-hexane. The precipitate was filtered and dried to provide poly[9-anthracenemethylacrylate/2-hydroxyethylacrylate/methylmethacrylate] copolymer of Formula 19. Yield: 80%.

Workup

  1. customThe reaction mixture was precipitated in ethyl ether
  2. filtrationThe precipitate was filtered
  3. customdried

Sources & evidence

ORD record
ord-b0792522f7da4e47a8b0fe58d7489fdd
Source dataset
uspto-grants-2002_12
Patent number
US06489432B2

Reaction notes

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