Potassium Cation → (tert-Butyl) 6-bromonicotinate

HRID 2337236Notes

Reaction equation

HRID 2337236 reaction equation
[Br:1][c:2]1[n:3][cH:4][c:5]([C:8](=[O:9])[OH:10])[cH:6][cH:7]1.[C:11]([Br:12])(=[O:13])[C:14]([Br:15])=[O:16].[CH2:31]1[O:32][CH2:33][CH2:34][CH2:35]1.[CH3:22][C:23]([CH3:24])([O-:25])[CH3:26].[CH3:36][CH2:37][O:38][C:39]([CH3:40])=[O:41].[CH3:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH3:48].[Cl:28][CH2:29][Cl:30].[K+:27].[O:17]=[CH:18][N:19]([CH3:20])[CH3:21]>>[Br:1][c:2]1[n:3][cH:4][c:5]([C:8](=[O:9])[O:10][C:23]([CH3:22])([CH3:24])[CH3:26])[cH:6][cH:7]1

Participants

10

Reactant 9

HCID 813Potassium CationHCID 6228DimethylformamideHCID 6344DichloromethaneHCID 8028TetrahydrofuranHCID 8857Ethyl AcetateHCID 8900HeptaneHCID 84841Ethanedioyl dibromideHCID 2389326-Bromonicotinic acidHCID 45749132-Methylpropan-2-olate

Product 1

HCID 26369925(tert-Butyl) 6-bromonicotinate

Sources & evidence

ORD record
ord-c4bd9c4c57f44b4cbe9e3f195d75ac36
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (10/10)

Reaction notes

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