Acetate → aldehydo-D-Xylose

HRID 2413020Notes

Reaction equation

HRID 2413020 reaction equation
[O:1]=[CH:2][C@@H:3]([C@H:5]([C@H:7]([CH2:9][OH:10])[OH:8])[OH:6])[OH:4].O=C[C@@H]([C@@H]([C@H]([C@H](C)O)O)O)O.O=C[C@@H]([C@H]([C@@H]([C@@H](CO)O)O)O)O.OCC([C@H]([C@@H]([C@@H](CO)O)O)O)=O.C(O)[C@H]1O[C@H](O[C@]2(CO)O[C@H](CO)[C@@H](O)[C@@H]2O)[C@H](O)[C@@H](O)[C@@H]1O.C(O)[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O.C([O-])(=O)C.C([O-])(=O)CC.C([O-])(=O)CCC.C([O-])(=O)C(C)O.OC1C=CC(C([O-])=O)=CC=1.NCCC(O)=O.N[C@H](C(O)=O)CC1N=CNC=1>C(O)C>[O:1]=[CH:2][C@@H:3]([C@H:5]([C@@H:7]([CH2:9][OH:10])[OH:8])[OH:6])[OH:4]

Participants

15

Reactant 13

HCID 175AcetateHCID 239Beta-AlanineHCID 5984D-(-)-FructoseHCID 5988SucroseHCID 10712D-(+)-Cellobiose (CNP0226604.15)HCID 19233(2R,3R,4S,5S)-2,3,4,5-tetrahydroxyhexanalHCID 91435LactateHCID 104745Propionate ionHCID 104775ButyrateHCID 107526(2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanalHCID 5460291aldehydo-L-arabinoseHCID 178419078HCID 178419078, compoundHCID 178524487HCID 178524487, compound

Product 1

HCID 644160aldehydo-D-Xylose

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

L-arabinose; L-rhamnose; D-glucose; D-fructose; sucrose; cellobiose; acetate; propionate; butyrate; DL-lactate; ethanol; para-hydroxybenzoate; β-alanine; L-histidine.

Sources & evidence

ORD record
ord-c376fcf42651482db18bd8ea6a6b3f81
Source dataset
uspto-grants-1985_01
Patent number
US04495284

Reaction notes

Loading…