Naphthalene → Naphthalene sodium

HRID 261002Notes

Reaction equation

HRID 261002 reaction equation
[CH:1]1[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH:4]=[CH:3][CH:2]=1.[Na:11].ClC1C=C(Cl)C=C(Cl)C=1N>O1CCCC1>[CH:9]1[C:10]2[C:5](=[CH:4][CH:3]=[CH:2][CH:1]=2)[CH:6]=[CH:7][CH:8]=1.[Na:11]

Participants

5

Reactant 3

HCID 931NaphthaleneHCID 124712,4,6-TrichloroanilineHCID 5360545Sodium

Product 1

HCID 66588811Naphthalene sodium

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

Sodium naphthalene was prepared from naphthalene (12.8 g., 0.1 mole), sodium (2.3 g., 0.1 g atom) and tetrahydrofuran (200 ml.). Thereafter, 2,4,6-trichloroaniline (19.6 g., 0.1 mole) was added under nitrogen at ice bath temperature.

Sources & evidence

ORD record
ord-b371c0a792f44983bf447eed26baf14e
Source dataset
uspto-grants-1979_08
Patent number
US04163659

Reaction notes

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