Dimethyl Sulfoxide → 1-(2-Azidopropyl)-8-(1-ethoxyethoxy)-1,7,8,9-tetrahydro-pyrano[2,3-g]indazole

HRID 288129Notes

Reaction equation

HRID 288129 reaction equation
[CH2:1]([CH3:2])[O:3][CH:4]([CH3:5])[O:6][CH:7]1[CH2:8][c:9]2[c:10]([cH:11][cH:12][c:13]3[cH:14][n:15][n:16]([CH2:18][CH:19]([CH3:20])[OH:21])[c:17]23)[O:22][CH2:23]1.[CH2:44]1[O:45][CH2:46][CH2:47][CH2:48]1.[CH3:24][CH2:25][N:26]([CH2:27][CH3:28])[CH2:29][CH3:30].[CH3:31][S:32]([O:33][S:34]([CH3:35])(=[O:36])=[O:37])(=[O:38])=[O:39].[CH3:49][S:50]([CH3:51])=[O:52].[N-:41]=[N+:42]=[N-:43].[Na+:40]>>[CH2:1]([CH3:2])[O:3][CH:4]([CH3:5])[O:6][CH:7]1[CH2:8][c:9]2[c:10]([cH:11][cH:12][c:13]3[cH:14][n:15][n:16]([CH2:18][CH:19]([CH3:20])[N:41]=[N+:42]=[N-:43])[c:17]23)[O:22][CH2:23]1

Participants

8

Reactant 7

HCID 679Dimethyl SulfoxideHCID 923Sodium ionHCID 8028TetrahydrofuranHCID 8471TriethylamineHCID 33558AzideHCID 81560Methanesulfonic anhydrideHCID 22496588HCID 22496588, compound

Product 1

HCID 224966011-(2-Azidopropyl)-8-(1-ethoxyethoxy)-1,7,8,9-tetrahydro-pyrano[2,3-g]indazole

Sources & evidence

ORD record
ord-c7ba4f0eb24b4cd89cac3e13debc22db
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (8/10)

Reaction notes

Loading…