Triethylamine → 6-Trimethylsilanylethynylbenzothiazol

HRID 294543Notes

Reaction equation

HRID 294543 reaction equation
[Br:7][c:8]1[cH:9][c:10]2[c:11]([n:12][cH:13][s:14]2)[cH:15][cH:16]1.[CH3:17][CH2:18][N:19]([CH2:20][CH3:21])[CH2:22][CH3:23].[CH3:1][Si:2]([CH3:3])([CH3:4])[C:5]#[CH:6].[Cu:24][I:25].[Pd:26]([Cl:27])[Cl:28].[c:29]1([P:30]([c:31]2[cH:32][cH:33][cH:34][cH:35][cH:36]2)[c:37]2[cH:38][cH:39][cH:40][cH:41][cH:42]2)[cH:43][cH:44][cH:45][cH:46][cH:47]1.[c:48]1([P:49]([c:50]2[cH:51][cH:52][cH:53][cH:54][cH:55]2)[c:56]2[cH:57][cH:58][cH:59][cH:60][cH:61]2)[cH:62][cH:63][cH:64][cH:65][cH:66]1>>[CH3:1][Si:2]([CH3:3])([CH3:4])[C:5]#[C:6][c:8]1[cH:9][c:10]2[c:11]([n:12][cH:13][s:14]2)[cH:15][cH:16]1

Participants

7

Reactant 6

HCID 8471TriethylamineHCID 11776Triphenylphosphine2×HCID 24290Palladium ChlorideHCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)HCID 66111TrimethylsilylacetyleneHCID 27951716-Bromo-1,3-benzothiazole

Product 1

HCID 231545826-Trimethylsilanylethynylbenzothiazol

Sources & evidence

ORD record
ord-e23ea6f2b4304a478977768a74454653
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (8/10)

Reaction notes

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