Chloride → 4'-Methyl-2-nitro-1,1'-biphenyl

HRID 297572Notes

Reaction equation

HRID 297572 reaction equation
[Br:1][c:2]1[cH:3][cH:4][c:5]([CH3:8])[cH:6][cH:7]1.[Br:24][c:25]1[c:26]([N+:31](=[O:32])[O-:33])[cH:27][cH:28][cH:29][cH:30]1.[C:9]([Li:10])([CH3:11])([CH3:12])[CH3:13].[CH2:15]([Al+:16][CH2:17][CH:18]([CH3:19])[CH3:20])[CH:21]([CH3:22])[CH3:23].[CH3:48][CH2:49][CH2:50][CH2:51][CH3:52].[CH3:53][c:54]1[cH:55][cH:56][cH:57][cH:58][cH:59]1.[Cl-:34].[H-:14].[O:43]1[CH2:44][CH2:45][CH2:46][CH2:47]1.[c:35]1([CH3:36])[cH:37][cH:38][cH:39][cH:40][c:41]1[Zn+:42]>>[c:2]1(-[c:25]2[c:26]([N+:31](=[O:32])[O-:33])[cH:27][cH:28][cH:29][cH:30]2)[cH:3][cH:4][c:5]([CH3:8])[cH:6][cH:7]1

Participants

11

Reactant 10

HCID 312ChlorideHCID 1140TolueneHCID 78054-BromotolueneHCID 8003PentaneHCID 8028TetrahydrofuranHCID 113411-Bromo-2-nitrobenzeneHCID 166653HydrideHCID 16686348Bis(2-methylpropyl)alumanyliumHCID 178418306HCID 178418306, compoundHCID 178424427HCID 178424427, compound

Product 1

HCID 104431944'-Methyl-2-nitro-1,1'-biphenyl

Sources & evidence

ORD record
ord-6e7de3eb297c4a4e9250768d6a99a13c
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (8/10)

Reaction notes

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