1-Octene → Biphenyl

HRID 357953Notes

Reaction equation

HRID 357953 reaction equation
C=CCCCCCC.Ic1ccccc1>CC1(C)c2cccc(P(c3ccccc3)c3ccccc3)c2Oc2c(P(c3ccccc3)c3ccccc3)cccc21.CCN(CC)CC.Cc1ccccc1.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.[Pd].[Pd]>c1ccc(-c2ccccc2)cc1.COc1cc(OC)cc(OC)c1.CCCCCC/C=C/c1ccccc1.C=C(CCCCCC)c1ccccc1

Participants

10

Reactant 2

HCID 81251-OcteneHCID 11575Iodobenzene

Product 4

HCID 7095BiphenylHCID 693011,3,5-TrimethoxybenzeneHCID 5369452HCID 5369452, compoundHCID 12396457(Oct-1-en-2-yl)benzene

Reagents, catalysts & solvents 4

HCID 8471TriethylamineReagentHCID 6360441,1'-(9,9-Dimethyl-9H-xanthene-4,5-diyl)bis(1,1-diphenylphosphine)CatalystHCID 1140TolueneSolventHCID 9811564Bis(dibenzylideneacetone)palladiumOther

Conditions

Temperature
85 °C

Workup

  1. additionKeep Filtrate

Sources & evidence

ORD record
ord-48beef99f7a24613a27b042cd3658ee6
Source dataset
1-octene Mizoroki-Heck

Reaction notes

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