1-Octene → Biphenyl

HRID 357994Notes

Reaction equation

HRID 357994 reaction equation
C=CCCCCCC.Ic1ccccc1>c1ccc(P(c2ccccc2)C23C4C5C6C2[Fe]56432789C3C2C7C8(P(c2ccccc2)c2ccccc2)C39)cc1.CCN(CC)CC.CN(C)C=O.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.[Pd].[Pd]>c1ccc(-c2ccccc2)cc1.COc1cc(OC)cc(OC)c1.CCCCCC/C=C/c1ccccc1.C=C(CCCCCC)c1ccccc1

Participants

10

Reactant 2

HCID 81251-OcteneHCID 11575Iodobenzene

Product 4

HCID 7095BiphenylHCID 693011,3,5-TrimethoxybenzeneHCID 5369452HCID 5369452, compoundHCID 12396457(Oct-1-en-2-yl)benzene

Reagents, catalysts & solvents 4

HCID 8471TriethylamineReagentHCID 178418185HCID 178418185, compoundCatalystHCID 6228DimethylformamideSolventHCID 9811564Bis(dibenzylideneacetone)palladiumOther

Conditions

Temperature
85 °C

Workup

  1. additionKeep Filtrate

Sources & evidence

ORD record
ord-7b1ebc8b07a14ff294bbd15478b7938d
Source dataset
1-octene Mizoroki-Heck

Reaction notes

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