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HRID400112

反应详情

EQUATION

反应方程式

HRID 400112 的结构方程式

REACTANTS

反应物

3
结构：CCOC(=O)CC(=O)OCC
HCID7761

Diethyl propanedioate

C7H12O4

结构：[H-].[Na+]
HCID24758

Sodium hydride

HNa

结构：ON=CC1=C(Cl)CCN(Cc2ccccc2)CC1
HCID86621673

未命名化合物

PRODUCTS

生成物

1
结构：CCOC(=O)c1c2c(c[n+]([O-])c1O)CCN(Cc1ccccc1)CC2
HCID178468432

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：[Cu][Br]
催化剂HCID24593

Copper(1+) bromide

BrCu

PROCEDURE

实验过程

Prepared from 1-benzyl-4-chloro-5-hydroxyiminomethyl-2,3,6,7-tetrahydro-1H-azepine by reaction with diethyl malonate in the presence of sodium hydride and catalytic amounts of copper(I) bromide at 100° C.