Hydrochloric Acid → o-Hydroxyphenyl methylcarbamate

HRID 485834Notes

Reaction equation

HRID 485834 reaction equation
CN.[C:3]([O:6][C:7]1[C:8](=[CH:10][CH:11]=[CH:12][CH:13]=1)[OH:9])(=O)[OH:4].[CH2:14]([N:16](CC)CC)C.Cl>C(Cl)Cl>[CH3:14][NH:16][C:3]([O:6][C:7]1[C:8](=[CH:10][CH:11]=[CH:12][CH:13]=1)[OH:9])=[O:4]

Participants

6

Reactant 4

HCID 313Hydrochloric AcidHCID 6329MethylamineHCID 8471TriethylamineHCID 13269093HCID 13269093, compound

Product 1

HCID 82537o-Hydroxyphenyl methylcarbamate

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

155 g of gaseous methylamine were fed into a solution of 680 g of pyrocatechol carbonate and 555 g of triethylamine in 2.5 liters of methylene chloride at 5° C., with vigorous stirring. 500 g of 36% strength hydrochloric acid were then added and the product was filtered off with suction and washed with water. 801 g (96% of the expected amount) of pyrocatechol methylcarbamate of melting point 125° C. were obtained.

Workup

  1. filtrationthe product was filtered off with suction
  2. washwashed with water

Sources & evidence

ORD record
ord-001923fd696c4864bc38ec8d342ec084
Source dataset
uspto-grants-1985_08
Patent number
US04537986

Reaction notes

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