Chloride → 4-[2-[[Tert-butyl(dimethyl)silyl]oxymethyl]-3-dimethylsilyloxy-4,4-dimethylpentoxy]-2,6-dichlorobenzaldehyde

HRID 683420Notes

Reaction equation

HRID 683420 reaction equation
[C:12]([CH3:13])([CH3:14])([CH3:15])[Si:16]([O:17][CH2:18][CH:19]([CH2:20][O:21][S:22]([CH3:23])(=[O:24])=[O:25])[CH:26]([O:27][SiH:28]([CH3:29])[CH3:30])[C:31]([CH3:32])([CH3:33])[CH3:34])([CH3:35])[CH3:36].[C:37](=[O:38])([O-:39])[O-:40].[CH3:63][N:64]([CH3:65])[CH:66]=[O:67].[CH3:68][CH2:69][O:70][C:71](=[O:72])[CH3:73].[Cl-:61].[Cl:1][c:2]1[c:3]([CH:4]=[O:5])[c:6]([Cl:11])[cH:7][c:8]([OH:10])[cH:9]1.[K+:41].[K+:42].[Na+:62].[O:43]1[CH2:44][CH2:45][O:46][CH2:47][CH2:48][O:49][CH2:50][CH2:51][O:52][CH2:53][CH2:54][O:55][CH2:56][CH2:57][O:58][CH2:59][CH2:60]1>>[Cl:1][c:2]1[c:3]([CH:4]=[O:5])[c:6]([Cl:11])[cH:7][c:8]([O:10][CH2:20][CH:19]([CH2:18][O:17][Si:16]([C:12]([CH3:13])([CH3:14])[CH3:15])([CH3:35])[CH3:36])[CH:26]([O:27][SiH:28]([CH3:29])[CH3:30])[C:31]([CH3:32])([CH3:33])[CH3:34])[cH:9]1

Participants

10

Reactant 9

HCID 312ChlorideHCID 813Potassium Cation2×HCID 923Sodium ionHCID 6228DimethylformamideHCID 8857Ethyl AcetateHCID 19660Carbonate IonHCID 2855718-Crown-6HCID 5283822,6-Dichloro-4-hydroxybenzaldehydeHCID 173174507[2-[[Tert-butyl(dimethyl)silyl]oxymethyl]-3-dimethylsilyloxy-4,4-dimethylpentyl] methanesulfonate

Product 1

HCID 1731774354-[2-[[Tert-butyl(dimethyl)silyl]oxymethyl]-3-dimethylsilyloxy-4,4-dimethylpentoxy]-2,6-dichlorobenzaldehyde

Sources & evidence

ORD record
ord-fb71f694092e46729a4531d7af997f44
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (3/10)

Reaction notes

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