Methanol → HCID 58387189, compound

HRID 687352Notes

Reaction equation

HRID 687352 reaction equation
[C:24](#[CH:25])[c:26]1[cH:27][cH:28][cH:29][cH:30][cH:31]1.[CH3:32][CH2:33][O:34][C:35]([CH3:36])=[O:37].[CH3:38][OH:39].[Cl:1][c:2]1[c:3]([I:23])[cH:4][c:5]2[c:6]([n:7]([CH2:14][O:15][CH2:16][CH2:17][Si:18]([CH3:19])([CH3:20])[CH3:21])[c:8]([S:10](=[O:11])(=[O:12])[CH3:13])[n:9]2)[cH:22]1.[Cu:45]([I:46])[I:47].[O:40]=[CH:41][N:42]([CH3:43])[CH3:44].[Pd:48]([Cl:49])[Cl:50].[c:51]1([P:52]([c:53]2[cH:54][cH:55][cH:56][cH:57][cH:58]2)[c:59]2[cH:60][cH:61][cH:62][cH:63][cH:64]2)[cH:65][cH:66][cH:67][cH:68][cH:69]1.[c:70]1([P:71]([c:72]2[cH:73][cH:74][cH:75][cH:76][cH:77]2)[c:78]2[cH:79][cH:80][cH:81][cH:82][cH:83]2)[cH:84][cH:85][cH:86][cH:87][cH:88]1>>[Cl:1][c:2]1[c:3]([C:25]#[C:24][c:26]2[cH:27][cH:28][cH:29][cH:30][cH:31]2)[cH:4][c:5]2[c:6]([n:7]([CH2:14][O:15][CH2:16][CH2:17][Si:18]([CH3:19])([CH3:20])[CH3:21])[c:8]([S:10](=[O:11])(=[O:12])[CH3:13])[n:9]2)[cH:22]1

Participants

9

Reactant 8

HCID 887MethanolHCID 6228DimethylformamideHCID 8857Ethyl AcetateHCID 10821PhenylacetyleneHCID 11776Triphenylphosphine2×HCID 24290Palladium ChlorideHCID 83717Copper iodideHCID 59267806HCID 59267806, compound

Product 1

HCID 58387189HCID 58387189, compound

Sources & evidence

ORD record
ord-4abf0abf843b4b509dff0f97dde3e3e0
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (3/10)

Reaction notes

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