proline dl-form → HCID 58508677, compound

HRID 799364Notes

Reaction equation

HRID 799364 reaction equation
[Br:20][c:21]1[cH:22][c:23]([N+:34](=[O:35])[O-:36])[c:24]([C:25](=[O:26])[O:27][C:28]([CH3:29])([CH3:30])[CH3:31])[cH:32][cH:33]1.[C:6](=[O:7])([O-:8])[O-:9].[CH3:40][CH2:41][O:42][C:43](=[O:44])[CH3:45].[CH3:46][S:47](=[O:48])[CH3:49].[Cu:37][I:38].[K+:10].[K+:11].[OH2:39].[OH:12][C:13]([CH:14]1[NH:15][CH2:16][CH2:17][CH2:18]1)=[O:19].[nH:1]1[n:2][cH:3][cH:4][cH:5]1>>[n:1]1(-[c:21]2[cH:22][c:23]([N+:34](=[O:35])[O-:36])[c:24]([C:25](=[O:26])[O:27][C:28]([CH3:29])([CH3:30])[CH3:31])[cH:32][cH:33]2)[n:2][cH:3][cH:4][cH:5]1

Participants

10

Reactant 9

HCID 614proline dl-formHCID 679Dimethyl SulfoxideHCID 813Potassium Cation2×HCID 962WaterHCID 1048PyrazoleHCID 8857Ethyl AcetateHCID 19660Carbonate IonHCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)HCID 26369829tert-Butyl 4-bromo-2-nitrobenzoate

Product 1

HCID 58508677HCID 58508677, compound

Sources & evidence

ORD record
ord-fddf038e927e4aa89513ac36227b7566
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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