Hydrochloric Acid → Methyl 2-oxotetrahydrofuran-3-carboxylate

HRID 802093Notes

Reaction equation

HRID 802093 reaction equation
[C:25]1(=[O:30])[CH2:26][CH2:27][CH2:28][O:29]1.[CH2:20]([Li:21])[CH2:22][CH2:23][CH3:24].[CH3:11][SiH:12]([CH3:13])[N:14]([CH3:15])[Si:16]([CH3:17])([CH3:18])[CH3:19].[CH3:1][Si:2]([CH3:3])([CH3:4])[N-:5][Si:6]([CH3:7])([CH3:8])[CH3:9].[CH3:31][O:32][C:33](=[O:34])[O:35][CH3:36].[ClH:37].[Li+:10].[O:38]1[CH2:39][CH2:40][CH2:41][CH2:42]1>>[C:25]1(=[O:30])[CH:26]([C:33]([O:32][CH3:31])=[O:34])[CH2:27][CH2:28][O:29]1

Participants

9

Reactant 8

HCID 313Hydrochloric AcidHCID 7302Gamma-ButyrolactoneHCID 8028TetrahydrofuranHCID 12021Dimethyl CarbonateHCID 28486Lithium ionHCID 589711N-dimethylsilyl-N-trimethylsilylmethanamineHCID 3280088Npc316347HCID 178418339Butyllithium

Product 1

HCID 315161Methyl 2-oxotetrahydrofuran-3-carboxylate

Sources & evidence

ORD record
ord-933cdfc394a54af68f0464055ee3c4b3
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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