Chloride → 2-Diethylphosphonomethyloxy-5-vinylnitrobenzene

HRID 812053Notes

Reaction equation

HRID 812053 reaction equation
[CH2:1]([CH3:2])[O:3][P:4](=[O:5])([O:6][CH2:7][CH3:8])[CH2:9][O:10][c:11]1[c:12]([N+:19](=[O:20])[O-:21])[cH:13][c:14]([O:17][CH3:18])[cH:15][cH:16]1.[CH2:22]([CH2:23][CH2:35][CH3:36])[Sn:24]([CH2:25][CH2:26][CH2:27][CH3:28])([CH2:29][CH2:30][CH2:31][CH3:32])[CH:33]=[CH2:34].[Cl-:42].[Cl-:43].[O:37]=[CH:38][N:39]([CH3:40])[CH3:41].[Pd+2:82].[c:44]1([P:45]([c:46]2[cH:47][cH:48][cH:49][cH:50][cH:51]2)[c:52]2[cH:53][cH:54][cH:55][cH:56][cH:57]2)[cH:58][cH:59][cH:60][cH:61][cH:62]1.[c:63]1([P:64]([c:65]2[cH:66][cH:67][cH:68][cH:69][cH:70]2)[c:71]2[cH:72][cH:73][cH:74][cH:75][cH:76]2)[cH:77][cH:78][cH:79][cH:80][cH:81]1>>[CH2:1]([CH3:2])[O:3][P:4](=[O:5])([O:6][CH2:7][CH3:8])[CH2:9][O:10][c:11]1[c:12]([N+:19](=[O:20])[O-:21])[cH:13][c:14]([CH:22]=[CH2:23])[cH:15][cH:16]1

Participants

7

Reactant 6

HCID 312Chloride2×HCID 6228DimethylformamideHCID 11776Triphenylphosphine2×HCID 81998TributylvinyltinHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 54481034HCID 54481034, compound

Product 1

HCID 541019582-Diethylphosphonomethyloxy-5-vinylnitrobenzene

Sources & evidence

ORD record
ord-cc6875137998412dbddda2498aabf157
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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