Ammonium → (5-Bromo-2-chlorobenzyloxy)triisopropylsilane

HRID 820153Notes

Reaction equation

HRID 820153 reaction equation
[Br:1][c:2]1[cH:3][cH:4][c:5]([Cl:10])[c:6]([CH2:7][OH:8])[cH:9]1.[CH3:22][N:23]([CH3:24])[CH:25]=[O:26].[CH3:27][N:28]([CH3:29])[c:30]1[cH:31][cH:32][n:33][cH:34][cH:35]1.[CH:11]([CH3:12])([CH3:13])[Si:14]([CH:15]([CH3:16])[CH3:17])([CH:18]([CH3:19])[CH3:20])[Cl:21].[Cl-:36].[NH4+:37]>>[Br:1][c:2]1[cH:3][cH:4][c:5]([Cl:10])[c:6]([CH2:7][O:8][Si:14]([CH:11]([CH3:12])[CH3:13])([CH:15]([CH3:16])[CH3:17])[CH:18]([CH3:19])[CH3:20])[cH:9]1

Participants

7

Reactant 6

HCID 223AmmoniumHCID 312ChlorideHCID 6228DimethylformamideHCID 142844-(Dimethylamino)pyridineHCID 139400Triisopropylsilyl chlorideHCID 5074766(5-Bromo-2-chlorophenyl)methanol

Product 1

HCID 67153939(5-Bromo-2-chlorobenzyloxy)triisopropylsilane

Sources & evidence

ORD record
ord-d234168086c64f568bb90a48c0cb22e8
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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