Triethoxysilane → HCID 22345873, compound

HRID 896954Notes

Reaction equation

HRID 896954 reaction equation
[C:1]([O:5][C:6]([CH3:9])([CH3:8])[CH3:7])(=[O:4])[CH:2]=[CH2:3].[CH2:10]([O:12][SiH:13]([O:17][CH2:18][CH3:19])[O:14][CH2:15][CH3:16])[CH3:11]>[H+].[H+].Cl[Pt-2](Cl)(Cl)(Cl)(Cl)Cl.O1CCCC1>[CH2:10]([O:12][Si:13]([O:17][CH2:18][CH3:19])([O:14][CH2:15][CH3:16])[CH2:3][CH2:2][C:1]([O:5][C:6]([CH3:9])([CH3:8])[CH3:7])=[O:4])[CH3:11]

Participants

5

Reactant 2

HCID 13830TriethoxysilaneHCID 15458tert-Butyl acrylate

Product 1

HCID 22345873HCID 22345873, compoundYield 1,000.2%

Reagents, catalysts & solvents 2

HCID 61859Chloroplatinic acidCatalystHCID 8028TetrahydrofuranSolvent

Procedure

Into the 100 ml of dried tetrahydrofuran, were fed 25.8 g (20 mmol) of t-butyl acrylate and 32.8 g (20 mmol) of triethoxysilane, and the mixture was substituted by argon. To the mixture solution, 10 mg of chloroplatinic acid was added and the mixture was heated for 24 hours under reflux. After completion of the reaction, 58.5 g of the objective compound was obtained by removing solvent.

Workup

  1. temperaturethe mixture was heated for 24 hours
  2. temperatureunder reflux
  3. customAfter completion of the reaction

Sources & evidence

ORD record
ord-312c12d8f12a47d2b1ce90b56e6e6412
Source dataset
uspto-grants-2005_07
Patent number
US06921623B2

Reaction notes

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