Butyl vinyl ether → Biphenyl

HRID 914556Notes

Reaction equation

HRID 914556 reaction equation
C1=C\CC/C=C\CC/1.C1=C\CC/C=C\CC/1.C=COCCCC.Ic1ccccc1.[Ni]>CCN(CC)CC.Cc1ccccc1.c1ccc(P(c2ccccc2)[C]23[CH]4[CH]5[CH]6[CH]2[Fe]56432789[CH]3[CH]2[CH]7[C]8(P(c2ccccc2)c2ccccc2)[CH]39)cc1>C=C(OCCCC)c1ccccc1.CCCCO/C=C/c1ccccc1.CCCCO/C=C\c1ccccc1.c1ccc(-c2ccccc2)cc1

Participants

11

Reactant 2

HCID 8108Butyl vinyl etherHCID 11575Iodobenzene

Product 5

HCID 7095BiphenylHCID 693011,3,5-TrimethoxybenzeneHCID 10464845(1-Butoxyethenyl)benzeneHCID 10464846HCID 10464846, compoundHCID 13834617HCID 13834617, compound

Reagents, catalysts & solvents 4

HCID 8471TriethylamineReagentHCID 178418185HCID 178418185, compoundCatalystHCID 1140TolueneSolventHCID 6433264Bis(1,5-cyclooctadiene)nickelOther

Conditions

Temperature
85 °C

Workup

  1. additionKeep Filtrate

Sources & evidence

ORD record
ord-9733410b073e4e11b2ac25701a0c8977
Source dataset
Vinyl ether Mizoroki-Heck

Reaction notes

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