Butyl vinyl ether → Biphenyl

HRID 914558Notes

Reaction equation

HRID 914558 reaction equation
C1=C\CC/C=C\CC/1.C1=C\CC/C=C\CC/1.C=COCCCC.Ic1ccccc1.[Ni]>CC(C)(C)[PH+](C(C)(C)C)C(C)(C)C.CCN(CC)CC.Cc1ccccc1.F[B-](F)(F)F>C=C(OCCCC)c1ccccc1.CCCCO/C=C/c1ccccc1.CCCCO/C=C\c1ccccc1.c1ccc(-c2ccccc2)cc1

Participants

11

Reactant 2

HCID 8108Butyl vinyl etherHCID 11575Iodobenzene

Product 5

HCID 7095BiphenylHCID 693011,3,5-TrimethoxybenzeneHCID 10464845(1-Butoxyethenyl)benzeneHCID 10464846HCID 10464846, compoundHCID 13834617HCID 13834617, compound

Reagents, catalysts & solvents 4

HCID 8471TriethylamineReagentHCID 2734635Tri-tert-butylphosphine tetrafluoroborateCatalystHCID 1140TolueneSolventHCID 6433264Bis(1,5-cyclooctadiene)nickelOther

Conditions

Temperature
85 °C

Workup

  1. additionKeep Filtrate

Sources & evidence

ORD record
ord-467b0c54263948d4932420fe23eec0fb
Source dataset
Vinyl ether Mizoroki-Heck

Reaction notes

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