Butyl vinyl ether → Biphenyl

HRID 914587Notes

Reaction equation

HRID 914587 reaction equation
C=COCCCC.Ic1ccccc1.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.[Pd].[Pd]>CC1(C)c2cccc(P(c3ccccc3)c3ccccc3)c2Oc2c(P(c3ccccc3)c3ccccc3)cccc21.CCN(CC)CC.Cc1ccccc1>C=C(OCCCC)c1ccccc1.CCCCO/C=C/c1ccccc1.CCCCO/C=C\c1ccccc1.c1ccc(-c2ccccc2)cc1

Participants

11

Reactant 2

HCID 8108Butyl vinyl etherHCID 11575Iodobenzene

Product 5

HCID 7095BiphenylHCID 693011,3,5-TrimethoxybenzeneHCID 10464845(1-Butoxyethenyl)benzeneHCID 10464846HCID 10464846, compoundHCID 13834617HCID 13834617, compound

Reagents, catalysts & solvents 4

HCID 8471TriethylamineReagentHCID 6360441,1'-(9,9-Dimethyl-9H-xanthene-4,5-diyl)bis(1,1-diphenylphosphine)CatalystHCID 1140TolueneSolventHCID 9811564Bis(dibenzylideneacetone)palladiumOther

Conditions

Temperature
85 °C

Workup

  1. additionKeep Filtrate

Sources & evidence

ORD record
ord-25d401c223f649ad96b671026eef9197
Source dataset
Vinyl ether Mizoroki-Heck

Reaction notes

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