Chloride → 2',4'-Dichlorobutyrophenone

HRID 946951Notes

Reaction equation

HRID 946951 reaction equation
[CH2:13]([CH2:14][CH3:15])[Mg+:16].[CH2:17]1[O:18][CH2:19][CH2:20][CH2:21]1.[Cl-:12].[Cl:1][c:2]1[c:3]([C:4](=[O:5])[Cl:6])[cH:7][cH:8][c:9]([Cl:11])[cH:10]1.[Cu:22][I:23]>>[Cl:1][c:2]1[c:3]([C:4](=[O:5])[CH2:13][CH2:14][CH3:15])[cH:7][cH:8][c:9]([Cl:11])[cH:10]1

Participants

6

Reactant 5

HCID 312ChlorideHCID 8028TetrahydrofuranHCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)HCID 666452,4-Dichlorobenzoyl chlorideHCID 178455847HCID 178455847, compound

Product 1

HCID 131756172',4'-Dichlorobutyrophenone

Sources & evidence

ORD record
ord-e5687a8b484d4ffd8f59eea175be1e5b
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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