Ammonium → n-[2-Benzyloxy-5-(2-bromo-1-hydroxy-ethyl)-phenyl]-methanesulfonamide

HRID 948564Notes

Reaction equation

HRID 948564 reaction equation
[BH3:48].[Br:1][CH2:2][C:3](=[O:4])[c:5]1[cH:6][c:7]([NH:19][S:20](=[O:21])(=[O:22])[CH3:23])[c:8]([O:11][CH2:12][c:13]2[cH:14][cH:15][cH:16][cH:17][cH:18]2)[cH:9][cH:10]1.[CH3:45][S:46][CH3:47].[CH3:56][CH2:57][O:58][C:59](=[O:60])[CH3:61].[Cl-:49].[NH4+:50].[O:51]1[CH2:52][CH2:53][CH2:54][CH2:55]1.[c:24]1([C:25]2([c:26]3[cH:27][cH:28][cH:29][cH:30][cH:31]3)[O:32][B:33]([CH3:34])[N:35]3[CH2:36][CH2:37][CH2:38][CH:39]23)[cH:40][cH:41][cH:42][cH:43][cH:44]1>>[Br:1][CH2:2][CH:3]([OH:4])[c:5]1[cH:6][c:7]([NH:19][S:20](=[O:21])(=[O:22])[CH3:23])[c:8]([O:11][CH2:12][c:13]2[cH:14][cH:15][cH:16][cH:17][cH:18]2)[cH:9][cH:10]1

Participants

9

Reactant 8

HCID 223AmmoniumHCID 312ChlorideHCID 1068Dimethyl SulfideHCID 6331BoraneHCID 8028TetrahydrofuranHCID 8857Ethyl AcetateHCID 5510901-Methyl-3,3-diphenyltetrahydro-3H-pyrrolo[1,2-c][1,3,2]oxazaboroleHCID 11200351N-[2-(benzyloxy)-5-(2-bromoacetyl)phenyl]methanesulfonamide

Product 1

HCID 22220535n-[2-Benzyloxy-5-(2-bromo-1-hydroxy-ethyl)-phenyl]-methanesulfonamide

Sources & evidence

ORD record
ord-efbd43a5e26a47bf99fdd4223d1908e7
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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